Given eqn-
$$x^2-pq x+(p+q)=0$$
Consider discriminant of the above equation
$$D=(pq)^2-(p+q)^2=-(p^2+q^2+pq)=-(p+\frac{q}{2})^2-\frac{3q^2}{4}\leq 0$$
$$Hence D\leq 0$$
But for roots to be real, D>=0 and hence D=0 which is possible only when p=q=0
Hence no pair of natural number (p,q) exists which satisfy the given condition.